Amido Black 10B CAS: 1064-48-8
Inombolo Yekhathalogu | XD90509 |
Igama lemveliso | Amido Black 10B |
CAS | 1064-48-8 |
Ifomula yeemolekyuli | C_{22}H_{14}N_{6}Na_{2}O_{9}S_{2} |
Ubunzima beMolekyuli | 616.4909 |
Iinkcukacha zokuGcina | I-Ambient |
IKhowudi yoMrhumo eHarmonized | 32041300 |
Ukucaciswa kweMveliso
Imbonakalo | Amandla |
Isivavanyi | 99% |
Ubude bamaza obuninzi bokufunxa (E1% kwiseli eyi-1 cm emanzini) | 616.0-621.0 nm |
Ukufunxa okuthe ngqo (E 1% kwiseli eyi-10 mm) ku-λ max. | (UMz.)460.0 |
Ukufunxa okuthe ngqo (E 1% kwiseli eyi-10 mm) ku-λ max. | (UMz.)460.0 |
I-Absorption Ratio (λmax-15nm/λmax+15nm) | 0.90-1.20 |
Ukuthotywa kwefotolytic yedayi ye-diazo, i-Amido Black, isebenzisa i-UV / H (2) O (2) iqhutywe ngokuvavanywa kwaye iiparameters zeyona nto isebenzayo yokuthotywa kwedayi imisiwe.Ukuthotywa kwedayi kwalandelwa yi-UV-Vis spectroscopy, i-HPLC, kunye ne-LC-MS kwaye kucetywayo ukuba iqaliswe () i-OH radicals eyenziwa yi-photolysis ye-H (2) O (2).Uphononongo oluneenkcukacha luye lwenziwa kusetyenziswa i-LC-MS kunye ne-LC-MS/MS ukumisela indlela yokuthotywa kwedayi kunye nokuchonga ezinye zeemveliso eziphakathi ezenziwe.Iziphumo zethu zibonisa ukuba ukuthotywa kwe-Amido Black kwenzeka ngokukhethwayo ngu ()OH uhlaselo olukhulu kwi-electron etyebileyo yokusebenza kwe-diazo ye-molecule.Ngaphezu koko, ubungqina buboniswa ukuba amanyathelo alandelayo kule ndlela yokuthotywa kwedayi ye-diazo ibandakanya i-radical denitration, i-radical desulfonation kunye ne-radical diazotization.Le ngxelo yenye yophononongo olumbalwa olucebise iindlela ezinobuchwephesha zeendlela zokuthotywa kwekhompawundi ye-diazo.