Iimveliso

(i-Benzylamine) i-trifluoroboron, ekwaziwa njenge-BnNH2 · BF3, sisixhobo esiluncedo kwi-organic synthesis kunye ne-catalysis.Yinto entsonkothileyo eyenziwe phakathi kwe-benzylamine kunye ne-boron trifluoride (BF3).Nantsi inkcazo yokusetyenziswa kwayo malunga namagama angama-300.Enye yezicelo eziphambili ze (benzylamine) trifluoroboron ikwinkalo yokwakhiwa kwebhondi ye-CN.Ingasetyenziselwa njenge-catalyst kwiimpendulo ezahlukeneyo zokudibanisa, ngokukodwa ekubunjweni kweebhondi ze-CN.Ezi mpendulo zibalulekile ekudityanisweni kwamayeza, amachiza eagrochemicals, kunye nezinye iikhemikhali ezilungileyo.I-(benzylamine) i-trifluoroboron complex isebenza njenge-precursor ye-intermediate esebenzayo enceda ukudibanisa i-nucleophiles kunye ne-aryl okanye i-alkyl halides, eyenza ukubunjwa kweebhondi ze-carbon-nitrogen.Oku kwakhiwa kwebhondi ye-CN kubalulekile ekwakhiweni kweemolekyuli ze-organic ezintsonkothileyo ezinezakhiwo ezinqwenelekayo nezisebenzayo.Isetyenziswa njengeqela elikhuselayo kwii-amines kwi-soli-phase peptide synthesis kunye ne-ligation yendalo yemichiza.I-(benzylamine)trifluoroboron complex isebenza njengeqela elikhuselayo elisusekayo elinokucandeka lula phantsi kweemeko ezithambileyo.Inika ukhuseleko oluthembekileyo kwiqela elisebenzayo le-amine ngexesha lokuguqulwa kweekhemikhali ezahlukeneyo ngelixa lihlala lizinzile ngexesha le-peptide synthesis.Emva kokuba i-synthesis igqityiwe, iqela elikhuselayo linokususwa ngokulula, livumela ukuveliswa kwe-peptide yendalo okanye izakhiwo zeprotheni.Ngaphezu koko, (benzylamine) i-trifluoroboron ifumana ukusetyenziswa kwintsimi ye-asymmetric synthesis.Ingaqeshwa njenge-organocatalyst kwiinguqu ezahlukeneyo ze-enantioselective.Ngenxa yobume bayo be-chiral, i-(benzylamine) i-trifluoroboron complex inokuphembelela i-stereochemistry ngexesha lokuphendula, ekhokelela ekwenziweni kweemveliso ezicocekileyo.Ingasetyenziswa kwiimpendulo ezifana ne-asymmetric aldol reactions, i-Mannich reactions, i-acylations, kunye nezinye i-carbon-carbon kunye ne-carbon-nitrogen bond-forming reactions.Iimpawu ze-organocatalytic ze (benzylamine) i-trifluoroboron zenza ukuba ibe sisixhobo esixabisekileyo kwi-synthesis ye-chiral intermediates kunye ne-pharmaceutical ingredients.Ngaphezu koko, (i-benzylamine) i-trifluoroboron ingasetyenziselwa ukulungelelanisa i-chemistry kunye nesayensi yezinto.Ingasebenza njengebhloko yokwakha kwi-synthesis ye-metal-organic frameworks (MOFs), izakhiwo zokulungelelanisa, kunye nezinye izinto zokusebenza.Ukulungelelaniswa kwe-(benzylamine) trifluoroboron kunye ne-ion zentsimbi kunika uzinzo kunye nokuqina kwezi zixhobo, ziphembelela iimpawu zazo zomzimba, iikhemikhali, kunye ne-catalytic.Ukukwazi ukubandakanya (i-benzylamine) i-trifluoroboron kwezi zixhobo ivula amathuba okuyilwa kunye nokuphuhliswa kwezinto ezintsha kunye nezicelo kwi-catalysis, ukugcinwa kwegesi, ukwahlukana, kunye nokuziva. i-organic synthesis kunye ne-catalysis.Ukusetyenziswa kwayo kwi-CN yokwakhiwa kwebhondi, i-peptide kunye neprotheni synthesis, i-asymmetric synthesis, kunye ne-chemistry yokulungelelanisa igxininisa ukubaluleka kwayo kwiinkalo ezahlukeneyo.I-(benzylamine) i-trifluoroboron complex ibonelela ngokusebenza okuphuculweyo kunye nokukhetha, okwenza udityaniso lweemolekyuli ze-organic ezintsonkothileyo, iikhompawundi ze-chiral, kunye nemathiriyeli esebenzayo.Iipropathi zayo zexabiso ziyenza ibe sisixhobo esibalulekileyo kubaphandi kwizifundiswa nakwimizi-mveliso esebenzela ukudibanisa imichiza emitsha, amayeza kunye nemathiriyeli.