I-Palladium,[1,3-bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene]chloro[(1,2,3-h)-(2E )-3-phenyl-2-propen-1-yl]-,stereoisomer Cas:884879-23-6
Inombolo Yekhathalogu | XD90699 |
Igama lemveliso | I-Palladium,[1,3-bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene]chloro[(1,2,3-h)-(2E )-3-phenyl-2-propen-1-yl]-,stereoisomer |
CAS | 884879-23-6 |
Ifomula yeemolekyuli | I-NeolystCX31 |
Ubunzima beMolekyuli | - |
Iinkcukacha zokuGcina | Ubushushu beGumbi |
Ukucaciswa kweMveliso
Isivavanyi | 99% |
Indawo yokunyibilika | 205-208°C |
Ukusetyenziswa kwesizukulwana sesibini [(NHC)Pd(R-allyl)Cl] izakhiwo ze-Suzuki-Miyaura kunye ne-Buchwald-Hartwig ezidibanisayo ezidibanisayo ezibandakanya i-heteroaromatic halides kwiqondo lokushisa lokushisa libikwa.Imizekelo yokuqala yobushushu begumbi i-Suzuki-Miyaura-ukudibanisa i-aryl chlorides engasebenziyo kunye ne-alkenyl boronic acids nazo zichazwe.Ukutshintshwa kwetheminali kwi-allyl moiety yekhompleksi ye-palladium iququzelela ukusebenza kwayo kwiqondo lobushushu legumbi elikhokelela kwiintlobo ze-catalytic ezisebenzayo zenza ukuba utshintsho olukhoyo lwenziwe ngokukhawuleza kusetyenziswa iimeko zokusabela ezinobulali kakhulu.Ukulayishwa kwe-Catalyst kunokuba ngaphantsi kwe-10 ppm ye-Buchwald-Hartwig aryl amination kunye ne-50 ppm ye-Suzuki-Miyaura reaction.