Pentamethylcyclopentadienyltris (acetonitrile)ruthenium(II) hexafluorophosphate Cas:99604-67-8 Umgubo oMthubi oOrenji
| Inombolo Yekhathalogu | XD90827 |
| Igama lemveliso | Pentamethylcyclopentadienyltris (acetonitrile)ruthenium(II) hexafluorophosphate |
| CAS | 99604-67-8 |
| Ifomula yeemolekyuli | I-C16H24F6N3PRu |
| Ubunzima beMolekyuli | 504.42 |
| Iinkcukacha zokuGcina | 2-8°C |
Ukucaciswa kweMveliso
| Imbonakalo | Umgubo oMthubi oOrenji |
| Isivavanyi | 99% |
I-complex [Cp*Ru(MeCN)3]PF6 iboniswa ukwenza i-hydrosilylation yoluhlu olubanzi lwe-alkynes.I-alkynes ye-terminal ikwazi ukufikelela kwiimveliso ze-alpha-vinylsilane kunye ne-regioselectivity elungileyo.Uphononongo lokuleyibhela kwe-Deuterium lubonisa inkqubo ecocekileyo yokongeza isemsebenzini.I-complex efanayo iyasebenza kwi-alkyne hydrosilylation yangaphakathi, apho ukhetho olupheleleyo lwenkqubo yokongeza i-trans kugcinwa.Iiklasi ezininzi zangaphakathi ze-alkyne substrate, kubandakanywa notywala be-propargylic kunye ne-alpha, iikhompawundi ze-beta-alkynyl carbonyl, zivumela ukubunjwa kwe-vinylsilane ye-regioselective.Ukunyamezela uluhlu olubanzi lwee-silanes kuyaphawuleka, kuquka i-alkyl-, i-aryl-, i-alkoxy-, kunye ne-halosilanes.Olu ncedo luboniswa ngokuthe ngqo kwi-triene substrates ye-silicon-tethered intramolecular Diels-Alder cycloadditions.
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